μ-Oxalato-κ4O1,O2:O 1′,O2′-bis[aqua(diethylene-triamine- κ3N)nickel(II)] bis(tetraphenylborate)

Lorena M. Callejo; Iñaki Muga; Pablo Vitoria; Santiago Reinoso; Pascual Román; Juan M. Gutiérrez-Zorrilla

doi:10.1107/S1600536803016362

μ-Oxalato-κ⁴O¹,O²:O ^1′,O^2′-bis[aqua(diethylene-triamine- κ³N)nickel(II)] bis(tetraphenylborate)

Lorena M. Callejo
, Iñaki Muga
, Pablo Vitoria
, Santiago Reinoso
, Pascual Román
, Juan M. Gutiérrez-Zorrilla^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [Ni₂(C₂O₄)(C ₄H₁₃N₃)₂(H₂O) ₂][B(C₆-H₅)₄]₂, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.

Original language	English
Pages (from-to)	m684-m686
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	8
DOIs	https://doi.org/10.1107/S1600536803016362
Publication status	Published - Aug 2003
Externally published	Yes

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title = "μ-Oxalato-κ4O1,O2:O 1′,O2′-bis[aqua(diethylene-triamine- κ3N)nickel(II)] bis(tetraphenylborate)",

abstract = "The title compound, [Ni2(C2O4)(C 4H13N3)2(H2O) 2][B(C6-H5)4]2, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.",

author = "Callejo, \{Lorena M.\} and I{\~n}aki Muga and Pablo Vitoria and Santiago Reinoso and Pascual Rom{\'a}n and Guti{\'e}rrez-Zorrilla, \{Juan M.\}",

year = "2003",

month = aug,

doi = "10.1107/S1600536803016362",

language = "English",

volume = "59",

pages = "m684--m686",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - μ-Oxalato-κ4O1,O2:O 1′,O2′-bis[aqua(diethylene-triamine- κ3N)nickel(II)] bis(tetraphenylborate)

AU - Callejo, Lorena M.

AU - Muga, Iñaki

AU - Vitoria, Pablo

AU - Reinoso, Santiago

AU - Román, Pascual

AU - Gutiérrez-Zorrilla, Juan M.

PY - 2003/8

Y1 - 2003/8

N2 - The title compound, [Ni2(C2O4)(C 4H13N3)2(H2O) 2][B(C6-H5)4]2, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.

AB - The title compound, [Ni2(C2O4)(C 4H13N3)2(H2O) 2][B(C6-H5)4]2, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.

UR - https://www.scopus.com/pages/publications/18444391155

U2 - 10.1107/S1600536803016362

DO - 10.1107/S1600536803016362

M3 - Article

AN - SCOPUS:18444391155

SN - 1600-5368

VL - 59

SP - m684-m686

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

μ-Oxalato-κ⁴O¹,O²:O ^1′,O^2′-bis[aqua(diethylene-triamine- κ³N)nickel(II)] bis(tetraphenylborate)

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