TY - JOUR
T1 - μ-Oxalato-κ4O1,O2:O 1′,O2′-bis[aqua(diethylene-triamine- κ3N)nickel(II)] bis(tetraphenylborate)
AU - Callejo, Lorena M.
AU - Muga, Iñaki
AU - Vitoria, Pablo
AU - Reinoso, Santiago
AU - Román, Pascual
AU - Gutiérrez-Zorrilla, Juan M.
PY - 2003/8
Y1 - 2003/8
N2 - The title compound, [Ni2(C2O4)(C 4H13N3)2(H2O) 2][B(C6-H5)4]2, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.
AB - The title compound, [Ni2(C2O4)(C 4H13N3)2(H2O) 2][B(C6-H5)4]2, contains a centrosymmetric dinuclear oxalato-nick-el(II) complex cation in which the oxalate ligand bridges the Ni atoms in a bis-bidentate fashion. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement, and by one O atom from a water molecule. Tetraphenylborate acts as the counter-anion. The crystal structure shows alternate cationic and anionic layers packed along the [101] direction.
UR - https://www.scopus.com/pages/publications/18444391155
U2 - 10.1107/S1600536803016362
DO - 10.1107/S1600536803016362
M3 - Article
AN - SCOPUS:18444391155
SN - 1600-5368
VL - 59
SP - m684-m686
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -