A New Perspective On Vanadyl Tartrate Dimers. Part Ii. Structure And Spectroscopic Properties Of Calcium Vanadyl Tartrate Tetrahydrate

Javier Garcia-Jaca; Teofilo Rojo; Jose L. Pizarro; Aintzane Goñi; Maria I. Arriortua

doi:10.1080/00958979308022766

A New Perspective On Vanadyl Tartrate Dimers. Part Ii. Structure And Spectroscopic Properties Of Calcium Vanadyl Tartrate Tetrahydrate

Javier Garcia-Jaca
, Teofilo Rojo^*
, Jose L. Pizarro
, Aintzane Goñi
, Maria I. Arriortua

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The calcium vanadyl tartrate complex [Ca(VO)(d,/-C₄H₂O₆)(H₂O)₄] has been synthesized and characterized by spectroscopic methods. Its crystal structure was solved by X-ray methods. The compound is monoclinic, space group P2₁/c, with a = 8.0282(5), b= 17.1568(8), c= 7.6113(3) A, β= 94.269(4)° and Z = 4. The structure consists of centrosymmetric vanadyl tartrate dimers, [(VO)(d,/-C₄H₂O₆)]₂^4-, and calcium cations placed between them. As a result, dimers form chains in the [101] direction. Neighbouring chains are linked by the coordination of the calcium ion to the oxygen atom of a vanadyl group of a different chain, thus forming a two-dimensional structure. Different layers are linked by hydrogen bonds. Spectroscopic studies show the existence of intra-dimeric interactions between vanadium atoms.

Original language	English
Pages (from-to)	327-336
Number of pages	10
Journal	Journal of Coordination Chemistry
Volume	30
Issue number	3-4
DOIs	https://doi.org/10.1080/00958979308022766
Publication status	Published - 1 Dec 1993
Externally published	Yes

Keywords

calcium
crystal structure
EPR
tartrate
Vanadyl

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10.1080/00958979308022766

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title = "A New Perspective On Vanadyl Tartrate Dimers. Part Ii. Structure And Spectroscopic Properties Of Calcium Vanadyl Tartrate Tetrahydrate",

abstract = "The calcium vanadyl tartrate complex [Ca(VO)(d,/-C4H2O6)(H2O)4] has been synthesized and characterized by spectroscopic methods. Its crystal structure was solved by X-ray methods. The compound is monoclinic, space group P21/c, with a = 8.0282(5), b= 17.1568(8), c= 7.6113(3) A, β= 94.269(4)° and Z = 4. The structure consists of centrosymmetric vanadyl tartrate dimers, [(VO)(d,/-C4H2O6)]24-, and calcium cations placed between them. As a result, dimers form chains in the [101] direction. Neighbouring chains are linked by the coordination of the calcium ion to the oxygen atom of a vanadyl group of a different chain, thus forming a two-dimensional structure. Different layers are linked by hydrogen bonds. Spectroscopic studies show the existence of intra-dimeric interactions between vanadium atoms.",

keywords = "calcium, crystal structure, EPR, tartrate, Vanadyl",

author = "Javier Garcia-Jaca and Teofilo Rojo and Pizarro, \{Jose L.\} and Aintzane Go{\~n}i and Arriortua, \{Maria I.\}",

year = "1993",

month = dec,

day = "1",

doi = "10.1080/00958979308022766",

language = "English",

volume = "30",

pages = "327--336",

journal = "Journal of Coordination Chemistry",

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T1 - A New Perspective On Vanadyl Tartrate Dimers. Part Ii. Structure And Spectroscopic Properties Of Calcium Vanadyl Tartrate Tetrahydrate

AU - Garcia-Jaca, Javier

AU - Rojo, Teofilo

AU - Pizarro, Jose L.

AU - Goñi, Aintzane

AU - Arriortua, Maria I.

PY - 1993/12/1

Y1 - 1993/12/1

N2 - The calcium vanadyl tartrate complex [Ca(VO)(d,/-C4H2O6)(H2O)4] has been synthesized and characterized by spectroscopic methods. Its crystal structure was solved by X-ray methods. The compound is monoclinic, space group P21/c, with a = 8.0282(5), b= 17.1568(8), c= 7.6113(3) A, β= 94.269(4)° and Z = 4. The structure consists of centrosymmetric vanadyl tartrate dimers, [(VO)(d,/-C4H2O6)]24-, and calcium cations placed between them. As a result, dimers form chains in the [101] direction. Neighbouring chains are linked by the coordination of the calcium ion to the oxygen atom of a vanadyl group of a different chain, thus forming a two-dimensional structure. Different layers are linked by hydrogen bonds. Spectroscopic studies show the existence of intra-dimeric interactions between vanadium atoms.

AB - The calcium vanadyl tartrate complex [Ca(VO)(d,/-C4H2O6)(H2O)4] has been synthesized and characterized by spectroscopic methods. Its crystal structure was solved by X-ray methods. The compound is monoclinic, space group P21/c, with a = 8.0282(5), b= 17.1568(8), c= 7.6113(3) A, β= 94.269(4)° and Z = 4. The structure consists of centrosymmetric vanadyl tartrate dimers, [(VO)(d,/-C4H2O6)]24-, and calcium cations placed between them. As a result, dimers form chains in the [101] direction. Neighbouring chains are linked by the coordination of the calcium ion to the oxygen atom of a vanadyl group of a different chain, thus forming a two-dimensional structure. Different layers are linked by hydrogen bonds. Spectroscopic studies show the existence of intra-dimeric interactions between vanadium atoms.

KW - calcium

KW - crystal structure

KW - EPR

KW - tartrate

KW - Vanadyl

UR - https://www.scopus.com/pages/publications/0009580279

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DO - 10.1080/00958979308022766

M3 - Article

AN - SCOPUS:0009580279

SN - 0095-8972

VL - 30

SP - 327

EP - 336

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 3-4

ER -

A New Perspective On Vanadyl Tartrate Dimers. Part Ii. Structure And Spectroscopic Properties Of Calcium Vanadyl Tartrate Tetrahydrate

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Keywords

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