A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses

Ana M. Gómez; Aitor Barrio; Ana Pedregosa; Serafín Valverde; J. Cristóbal López

doi:10.1016/j.tetlet.2003.09.101

A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses

Ana M. Gómez^*
, Aitor Barrio
, Ana Pedregosa
, Serafín Valverde
, J. Cristóbal López

^*Corresponding author for this work

CSIC - Instituto de Química Orgánica General IQOG

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The reaction of aldehydes with allylzinc reagents resulting from the umpolung of π-allyl palladium complexes from 1-exo-methylene 2,3-anhydrofuranoses provides a novel entry to C-glycals.

Original language	English
Pages (from-to)	8433-8435
Number of pages	3
Journal	Tetrahedron Letters
Volume	44
Issue number	46
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.101
Publication status	Published - 10 Nov 2003
Externally published	Yes

Keywords

Allylation
C-glycals
Carbohydrates
Palladium
Zinc

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10.1016/j.tetlet.2003.09.101

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title = "A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses",

abstract = "The reaction of aldehydes with allylzinc reagents resulting from the umpolung of π-allyl palladium complexes from 1-exo-methylene 2,3-anhydrofuranoses provides a novel entry to C-glycals.",

keywords = "Allylation, C-glycals, Carbohydrates, Palladium, Zinc",

author = "G{\'o}mez, \{Ana M.\} and Aitor Barrio and Ana Pedregosa and Seraf{\'i}n Valverde and L{\'o}pez, \{J. Crist{\'o}bal\}",

year = "2003",

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day = "10",

doi = "10.1016/j.tetlet.2003.09.101",

language = "English",

volume = "44",

pages = "8433--8435",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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TY - JOUR

T1 - A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses

AU - Gómez, Ana M.

AU - Barrio, Aitor

AU - Pedregosa, Ana

AU - Valverde, Serafín

AU - López, J. Cristóbal

PY - 2003/11/10

Y1 - 2003/11/10

N2 - The reaction of aldehydes with allylzinc reagents resulting from the umpolung of π-allyl palladium complexes from 1-exo-methylene 2,3-anhydrofuranoses provides a novel entry to C-glycals.

AB - The reaction of aldehydes with allylzinc reagents resulting from the umpolung of π-allyl palladium complexes from 1-exo-methylene 2,3-anhydrofuranoses provides a novel entry to C-glycals.

KW - Allylation

KW - C-glycals

KW - Carbohydrates

KW - Palladium

KW - Zinc

UR - https://www.scopus.com/pages/publications/0141922093

U2 - 10.1016/j.tetlet.2003.09.101

DO - 10.1016/j.tetlet.2003.09.101

M3 - Article

AN - SCOPUS:0141922093

SN - 0040-4039

VL - 44

SP - 8433

EP - 8435

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

A novel entry to C-glycals via diethylzinc-mediated umpolung of π-allyl palladium derived from 1-exo-methylene 2,3-anhydrofuranoses

Abstract

Keywords

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