A phosphine-stabilized silylene rhodium complex

N. Almenara; J. I. Miranda; A. Rodríguez-Diéguez; M. A. Garralda; M. A. Huertos

doi:10.1039/c9dt04071d

A phosphine-stabilized silylene rhodium complex

N. Almenara
, J. I. Miranda
, A. Rodríguez-Diéguez
, M. A. Garralda
, M. A. Huertos^*

^*Corresponding author for this work

Department of Applied Chemistry
University of Granada

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.

Original language	English
Pages (from-to)	17179-17183
Number of pages	5
Journal	Dalton Transactions
Volume	48
Issue number	46
DOIs	https://doi.org/10.1039/c9dt04071d
Publication status	Published - 2019
Externally published	Yes

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title = "A phosphine-stabilized silylene rhodium complex",

abstract = "The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.",

author = "N. Almenara and Miranda, \{J. I.\} and A. Rodr{\'i}guez-Di{\'e}guez and Garralda, \{M. A.\} and Huertos, \{M. A.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9dt04071d",

language = "English",

volume = "48",

pages = "17179--17183",

journal = "Dalton Transactions",

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TY - JOUR

T1 - A phosphine-stabilized silylene rhodium complex

AU - Almenara, N.

AU - Miranda, J. I.

AU - Rodríguez-Diéguez, A.

AU - Garralda, M. A.

AU - Huertos, M. A.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.

AB - The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade.

UR - https://www.scopus.com/pages/publications/85075731660

U2 - 10.1039/c9dt04071d

DO - 10.1039/c9dt04071d

M3 - Article

C2 - 31729513

AN - SCOPUS:85075731660

SN - 1477-9226

VL - 48

SP - 17179

EP - 17183

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

A phosphine-stabilized silylene rhodium complex

Abstract

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