Carbons supported bio-ionic liquids: Stability and catalytic activity

Eduardo J. García-Suárez; Patricia Moriel; Carmen Menéndez-Vázquez; Miguel A. Montes-Morán; Ana B. García

doi:10.1016/j.micromeso.2011.04.023

Carbons supported bio-ionic liquids: Stability and catalytic activity

Eduardo J. García-Suárez^*
, Patricia Moriel
, Carmen Menéndez-Vázquez
, Miguel A. Montes-Morán
, Ana B. García

^*Corresponding author for this work

Instituto Nacional Del Carbón (CSIC)

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

[Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.

Original language	English
Pages (from-to)	205-208
Number of pages	4
Journal	Microporous and Mesoporous Materials
Volume	144
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2011.04.023
Publication status	Published - Oct 2011
Externally published	Yes

Keywords

Carbon materials
Heterogeneous organocatalysis
Michael addition
Supported Bio-IL
[Chol][Pro]

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10.1016/j.micromeso.2011.04.023

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title = "Carbons supported bio-ionic liquids: Stability and catalytic activity",

abstract = "[Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.",

keywords = "Carbon materials, Heterogeneous organocatalysis, Michael addition, Supported Bio-IL, [Chol][Pro]",

author = "Garc{\'i}a-Su{\'a}rez, \{Eduardo J.\} and Patricia Moriel and Carmen Men{\'e}ndez-V{\'a}zquez and Montes-Mor{\'a}n, \{Miguel A.\} and Garc{\'i}a, \{Ana B.\}",

year = "2011",

month = oct,

doi = "10.1016/j.micromeso.2011.04.023",

language = "English",

volume = "144",

pages = "205--208",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

number = "1-3",

}

TY - JOUR

T1 - Carbons supported bio-ionic liquids

T2 - Stability and catalytic activity

AU - García-Suárez, Eduardo J.

AU - Moriel, Patricia

AU - Menéndez-Vázquez, Carmen

AU - Montes-Morán, Miguel A.

AU - García, Ana B.

PY - 2011/10

Y1 - 2011/10

N2 - [Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.

AB - [Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.

KW - Carbon materials

KW - Heterogeneous organocatalysis

KW - Michael addition

KW - Supported Bio-IL

KW - [Chol][Pro]

UR - https://www.scopus.com/pages/publications/79960198769

U2 - 10.1016/j.micromeso.2011.04.023

DO - 10.1016/j.micromeso.2011.04.023

M3 - Article

AN - SCOPUS:79960198769

SN - 1387-1811

VL - 144

SP - 205

EP - 208

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Carbons supported bio-ionic liquids: Stability and catalytic activity

Abstract

Keywords

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