Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene

M. Ibañez; E. Epelde; P. Castaño; M. Gamero; A. T. Aguayo; A. G. Gayubo; J. Bilbao

Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene

M. Ibañez
, E. Epelde^*
, P. Castaño
, M. Gamero
, A. T. Aguayo
, A. G. Gayubo
, J. Bilbao

^*Corresponding author for this work

Research output: Contribution to conference › Paper › peer-review

Abstract

Deactivation by coke of a HZSM-5 zeolite and severe shape selectivity catalysts (SAPO-18 and SAPO-34) were studied in the cracking of 1-butene. The coke was characterized and the effect of shape selectivity and different acidity of the catalysts on the coke composition and structure were determined. SAPO-18 and SAPO-34 catalysts exhibited higher severity of shape selectivity than the HZSM-5 zeolite. The yields of non-aromatic C₅₊ and BTX lumps decreased due to steric limitations. High values of propylene yield and selectivity were observed in the case of SAPO-18 and SAPO-34 compared to those obtained with the HZSM-5 zeolite. SAPO-34 was more active and gave a higher yield of propylene than that of the SAPO-18. The deactivation of SAPO-34 is faster than that for the SAPO-18. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012).

Original language	English
Publication status	Published - 2012
Externally published	Yes
Event	20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012 - Prague, Czech Republic Duration: 25 Aug 2012 → 29 Aug 2012

Conference

Conference	20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012
Country/Territory	Czech Republic
City	Prague
Period	25/08/12 → 29/08/12

Cite this

Ibañez, M., Epelde, E., Castaño, P., Gamero, M., Aguayo, A. T., Gayubo, A. G., & Bilbao, J. (2012). Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene. Paper presented at 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012, Prague, Czech Republic.

Ibañez, M. ; Epelde, E. ; Castaño, P. et al. / Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene. Paper presented at 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012, Prague, Czech Republic.

@conference{ddbc73ea34a64d4eb5fb9a2b07339cbe,

title = "Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene",

abstract = "Deactivation by coke of a HZSM-5 zeolite and severe shape selectivity catalysts (SAPO-18 and SAPO-34) were studied in the cracking of 1-butene. The coke was characterized and the effect of shape selectivity and different acidity of the catalysts on the coke composition and structure were determined. SAPO-18 and SAPO-34 catalysts exhibited higher severity of shape selectivity than the HZSM-5 zeolite. The yields of non-aromatic C5+ and BTX lumps decreased due to steric limitations. High values of propylene yield and selectivity were observed in the case of SAPO-18 and SAPO-34 compared to those obtained with the HZSM-5 zeolite. SAPO-34 was more active and gave a higher yield of propylene than that of the SAPO-18. The deactivation of SAPO-34 is faster than that for the SAPO-18. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012).",

author = "M. Iba{\~n}ez and E. Epelde and P. Casta{\~n}o and M. Gamero and Aguayo, \{A. T.\} and Gayubo, \{A. G.\} and J. Bilbao",

year = "2012",

language = "English",

note = "20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012 ; Conference date: 25-08-2012 Through 29-08-2012",

}

Ibañez, M, Epelde, E, Castaño, P, Gamero, M, Aguayo, AT, Gayubo, AG & Bilbao, J 2012, 'Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene', Paper presented at 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012, Prague, Czech Republic, 25/08/12 - 29/08/12.

Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene. / Ibañez, M.; Epelde, E.; Castaño, P. et al.
2012. Paper presented at 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012, Prague, Czech Republic.

Research output: Contribution to conference › Paper › peer-review

TY - CONF

T1 - Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene

AU - Ibañez, M.

AU - Epelde, E.

AU - Castaño, P.

AU - Gamero, M.

AU - Aguayo, A. T.

AU - Gayubo, A. G.

AU - Bilbao, J.

PY - 2012

Y1 - 2012

N2 - Deactivation by coke of a HZSM-5 zeolite and severe shape selectivity catalysts (SAPO-18 and SAPO-34) were studied in the cracking of 1-butene. The coke was characterized and the effect of shape selectivity and different acidity of the catalysts on the coke composition and structure were determined. SAPO-18 and SAPO-34 catalysts exhibited higher severity of shape selectivity than the HZSM-5 zeolite. The yields of non-aromatic C5+ and BTX lumps decreased due to steric limitations. High values of propylene yield and selectivity were observed in the case of SAPO-18 and SAPO-34 compared to those obtained with the HZSM-5 zeolite. SAPO-34 was more active and gave a higher yield of propylene than that of the SAPO-18. The deactivation of SAPO-34 is faster than that for the SAPO-18. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012).

AB - Deactivation by coke of a HZSM-5 zeolite and severe shape selectivity catalysts (SAPO-18 and SAPO-34) were studied in the cracking of 1-butene. The coke was characterized and the effect of shape selectivity and different acidity of the catalysts on the coke composition and structure were determined. SAPO-18 and SAPO-34 catalysts exhibited higher severity of shape selectivity than the HZSM-5 zeolite. The yields of non-aromatic C5+ and BTX lumps decreased due to steric limitations. High values of propylene yield and selectivity were observed in the case of SAPO-18 and SAPO-34 compared to those obtained with the HZSM-5 zeolite. SAPO-34 was more active and gave a higher yield of propylene than that of the SAPO-18. The deactivation of SAPO-34 is faster than that for the SAPO-18. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012).

UR - https://www.scopus.com/pages/publications/84874926755

M3 - Paper

AN - SCOPUS:84874926755

T2 - 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012

Y2 - 25 August 2012 through 29 August 2012

ER -

Ibañez M, Epelde E, Castaño P, Gamero M, Aguayo AT, Gayubo AG et al.. Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene. 2012. Paper presented at 20th International Congress of Chemical and Process Engineering, CHISA 2012 and 15th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2012, Prague, Czech Republic.

Coke deactivation of HZSM-5, SAPO-18 and SAPO-34 catalysts in the selective production of propylene from n-butene

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