Cure chemo-rheology of mixtures based on epoxy resins and ester cyanates

M. D. Martin; M. Ormaetxea; I. Harismendy; P. M. Remiro; I. Mondragon

doi:10.1016/S0014-3057(98)00095-0

Cure chemo-rheology of mixtures based on epoxy resins and ester cyanates

M. D. Martin
, M. Ormaetxea
, I. Harismendy
, P. M. Remiro
, I. Mondragon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Tetrafunctional epoxy and ester cyanate resins were cured together at several temperatures. Mixtures were investigated at different stoichiometric ratios. FTIR investigation of these systems through curing allowed us to analyze the reaction pathway of these reactive systems. Isothermal measurements performed by FTIR spectroscopy indicated that the curing reactions were dependent on the stoichiometric ratio of the mixtures. Differential scanning calorimetry (DSC) showed the dilution effect of the epoxy resin in the cyclotrimerization of the catalyzed cyanate ester resin and also the existence of several reactions during polymerization of the mixtures. Rheological characterization of the curing process indicated an evident delay of the vitrification time as epoxy content in the mixtures increased.

Original language	English
Pages (from-to)	57-68
Number of pages	12
Journal	European Polymer Journal
Volume	35
Issue number	1
DOIs	https://doi.org/10.1016/S0014-3057(98)00095-0
Publication status	Published - 1999
Externally published	Yes

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title = "Cure chemo-rheology of mixtures based on epoxy resins and ester cyanates",

abstract = "Tetrafunctional epoxy and ester cyanate resins were cured together at several temperatures. Mixtures were investigated at different stoichiometric ratios. FTIR investigation of these systems through curing allowed us to analyze the reaction pathway of these reactive systems. Isothermal measurements performed by FTIR spectroscopy indicated that the curing reactions were dependent on the stoichiometric ratio of the mixtures. Differential scanning calorimetry (DSC) showed the dilution effect of the epoxy resin in the cyclotrimerization of the catalyzed cyanate ester resin and also the existence of several reactions during polymerization of the mixtures. Rheological characterization of the curing process indicated an evident delay of the vitrification time as epoxy content in the mixtures increased.",

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T1 - Cure chemo-rheology of mixtures based on epoxy resins and ester cyanates

AU - Martin, M. D.

AU - Ormaetxea, M.

AU - Harismendy, I.

AU - Remiro, P. M.

AU - Mondragon, I.

PY - 1999

Y1 - 1999

N2 - Tetrafunctional epoxy and ester cyanate resins were cured together at several temperatures. Mixtures were investigated at different stoichiometric ratios. FTIR investigation of these systems through curing allowed us to analyze the reaction pathway of these reactive systems. Isothermal measurements performed by FTIR spectroscopy indicated that the curing reactions were dependent on the stoichiometric ratio of the mixtures. Differential scanning calorimetry (DSC) showed the dilution effect of the epoxy resin in the cyclotrimerization of the catalyzed cyanate ester resin and also the existence of several reactions during polymerization of the mixtures. Rheological characterization of the curing process indicated an evident delay of the vitrification time as epoxy content in the mixtures increased.

AB - Tetrafunctional epoxy and ester cyanate resins were cured together at several temperatures. Mixtures were investigated at different stoichiometric ratios. FTIR investigation of these systems through curing allowed us to analyze the reaction pathway of these reactive systems. Isothermal measurements performed by FTIR spectroscopy indicated that the curing reactions were dependent on the stoichiometric ratio of the mixtures. Differential scanning calorimetry (DSC) showed the dilution effect of the epoxy resin in the cyclotrimerization of the catalyzed cyanate ester resin and also the existence of several reactions during polymerization of the mixtures. Rheological characterization of the curing process indicated an evident delay of the vitrification time as epoxy content in the mixtures increased.

UR - https://www.scopus.com/pages/publications/0002302118

U2 - 10.1016/S0014-3057(98)00095-0

DO - 10.1016/S0014-3057(98)00095-0

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SN - 0014-3057

VL - 35

SP - 57

EP - 68

JO - European Polymer Journal

JF - European Polymer Journal

IS - 1

ER -

Cure chemo-rheology of mixtures based on epoxy resins and ester cyanates

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