Direct Synthesis of Enolizable N-Sulfonyl Ketimines under Microwave Irradiation

Pablo Ortiz; Juan F. Collados; Syuzanna R. Harutyunyan

doi:10.1002/ejoc.201600022

Direct Synthesis of Enolizable N-Sulfonyl Ketimines under Microwave Irradiation

Pablo Ortiz, Juan F. Collados, Syuzanna R. Harutyunyan^*

^*Corresponding author for this work

Bioeconomy and CO2

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

N-sulfonyl imines are widely used as substrates for a range of transformations. Access to N-sulfonyl aldimines is straightforward through direct condensation between the parent aldehyde and the sulfonamide. However, this approach is not efficient for the synthesis of enolizable N-sulfonyl ketimines. Herein we report a rapid and facile methodology for obtaining these products using microwave irradiation.

Original language	English
Pages (from-to)	1247-1250
Number of pages	4
Journal	European Journal of Organic Chemistry
Volume	2016
Issue number	7
DOIs	https://doi.org/10.1002/ejoc.201600022
Publication status	Published - 1 Mar 2016

Keywords

Condensation reactions
Imines
Ketimines
Microwave chemistry

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10.1002/ejoc.201600022

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title = "Direct Synthesis of Enolizable N-Sulfonyl Ketimines under Microwave Irradiation",

abstract = "N-sulfonyl imines are widely used as substrates for a range of transformations. Access to N-sulfonyl aldimines is straightforward through direct condensation between the parent aldehyde and the sulfonamide. However, this approach is not efficient for the synthesis of enolizable N-sulfonyl ketimines. Herein we report a rapid and facile methodology for obtaining these products using microwave irradiation.",

keywords = "Condensation reactions, Imines, Ketimines, Microwave chemistry",

author = "Pablo Ortiz and Collados, \{Juan F.\} and Harutyunyan, \{Syuzanna R.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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T1 - Direct Synthesis of Enolizable N-Sulfonyl Ketimines under Microwave Irradiation

AU - Ortiz, Pablo

AU - Collados, Juan F.

AU - Harutyunyan, Syuzanna R.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - N-sulfonyl imines are widely used as substrates for a range of transformations. Access to N-sulfonyl aldimines is straightforward through direct condensation between the parent aldehyde and the sulfonamide. However, this approach is not efficient for the synthesis of enolizable N-sulfonyl ketimines. Herein we report a rapid and facile methodology for obtaining these products using microwave irradiation.

AB - N-sulfonyl imines are widely used as substrates for a range of transformations. Access to N-sulfonyl aldimines is straightforward through direct condensation between the parent aldehyde and the sulfonamide. However, this approach is not efficient for the synthesis of enolizable N-sulfonyl ketimines. Herein we report a rapid and facile methodology for obtaining these products using microwave irradiation.

KW - Condensation reactions

KW - Imines

KW - Ketimines

KW - Microwave chemistry

UR - https://www.scopus.com/pages/publications/84960428399

U2 - 10.1002/ejoc.201600022

DO - 10.1002/ejoc.201600022

M3 - Article

AN - SCOPUS:84960428399

SN - 1434-193X

VL - 2016

SP - 1247

EP - 1250

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 7

ER -

Direct Synthesis of Enolizable N-Sulfonyl Ketimines under Microwave Irradiation

Abstract

Keywords

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