Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

María I. Mangione; Rolando A. Spanevello; Daniela Minudri; Daniel Heredia; Luciana Fernandez; Luis Otero; Fernando Fungo

doi:10.1016/j.electacta.2016.04.154

Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

María I. Mangione
, Rolando A. Spanevello^*
, Daniela Minudri
, Daniel Heredia
, Luciana Fernandez
, Luis Otero
, Fernando Fungo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

Original language	English
Pages (from-to)	143-151
Number of pages	9
Journal	Electrochimica Acta
Volume	207
DOIs	https://doi.org/10.1016/j.electacta.2016.04.154
Publication status	Published - 20 Jul 2016
Externally published	Yes

Keywords

Dendrimeric Polymers
Electrodeposition
Optoelectronic

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10.1016/j.electacta.2016.04.154

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@article{219153262381480ca7c956bd63f9ac89,

title = "Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films",

abstract = "A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.",

keywords = "Dendrimeric Polymers, Electrodeposition, Optoelectronic",

author = "Mangione, \{Mar{\'i}a I.\} and Spanevello, \{Rolando A.\} and Daniela Minudri and Daniel Heredia and Luciana Fernandez and Luis Otero and Fernando Fungo",

year = "2016",

month = jul,

day = "20",

doi = "10.1016/j.electacta.2016.04.154",

language = "English",

volume = "207",

pages = "143--151",

journal = "Electrochimica Acta",

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T1 - Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

AU - Mangione, María I.

AU - Spanevello, Rolando A.

AU - Minudri, Daniela

AU - Heredia, Daniel

AU - Fernandez, Luciana

AU - Otero, Luis

AU - Fungo, Fernando

PY - 2016/7/20

Y1 - 2016/7/20

N2 - A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

AB - A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

KW - Dendrimeric Polymers

KW - Electrodeposition

KW - Optoelectronic

UR - https://www.scopus.com/pages/publications/84966297187

U2 - 10.1016/j.electacta.2016.04.154

DO - 10.1016/j.electacta.2016.04.154

M3 - Article

AN - SCOPUS:84966297187

SN - 0013-4686

VL - 207

SP - 143

EP - 151

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

Abstract

Keywords

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