Evolution of tribologically induced chemical and structural degradation in hydrogenated a-C coatings

Roman Nevshupa; Jaume Caro; Alba Arratibel; Raül Bonet; Anton Rusanov; Jose Ramon Ares; Elisa Roman

doi:10.1016/j.triboint.2018.08.023

Evolution of tribologically induced chemical and structural degradation in hydrogenated a-C coatings

Roman Nevshupa, Jaume Caro, Alba Arratibel, Raül Bonet, Anton Rusanov, Jose Ramon Ares, Elisa Roman

Membrane Technology and Intensification of Processes

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The coatings with gradually varying chemical composition and structure were obtained by PECVD method from methane precursor and various admixtures of Ar. The composition of emitted gases and triboemission behaviour were studied for these coatings and correlated with the coating properties and deposition conditions. A new analytical approach was developed that allowed identification of the emitted gas species with much higher accuracy than conventional techniques. For the first time, triboemission of alkanes higher than propane was observed. By the application of kinetic model to the analysis of triboemission time series, chemical and structural degradation in carbon coatings could be traced in course of tribological tests.

Original language	English
Pages (from-to)	177-190
Number of pages	14
Journal	Tribology International
Volume	129
DOIs	https://doi.org/10.1016/j.triboint.2018.08.023
Publication status	Published - Jan 2019

Keywords

Degradation
Hydrogenated amorphous carbon
Mass-spectrometry
Tribochemistry

Access to Document

10.1016/j.triboint.2018.08.023

Cite this

@article{183059ab42ff4aff96e76381c9ec685d,

title = "Evolution of tribologically induced chemical and structural degradation in hydrogenated a-C coatings",

abstract = "The coatings with gradually varying chemical composition and structure were obtained by PECVD method from methane precursor and various admixtures of Ar. The composition of emitted gases and triboemission behaviour were studied for these coatings and correlated with the coating properties and deposition conditions. A new analytical approach was developed that allowed identification of the emitted gas species with much higher accuracy than conventional techniques. For the first time, triboemission of alkanes higher than propane was observed. By the application of kinetic model to the analysis of triboemission time series, chemical and structural degradation in carbon coatings could be traced in course of tribological tests.",

keywords = "Degradation, Hydrogenated amorphous carbon, Mass-spectrometry, Tribochemistry",

author = "Roman Nevshupa and Jaume Caro and Alba Arratibel and Ra{\"u}l Bonet and Anton Rusanov and Ares, {Jose Ramon} and Elisa Roman",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = jan,

doi = "10.1016/j.triboint.2018.08.023",

language = "English",

volume = "129",

pages = "177--190",

journal = "Tribology International",

issn = "0301-679X",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Evolution of tribologically induced chemical and structural degradation in hydrogenated a-C coatings

AU - Nevshupa, Roman

AU - Caro, Jaume

AU - Arratibel, Alba

AU - Bonet, Raül

AU - Rusanov, Anton

AU - Ares, Jose Ramon

AU - Roman, Elisa

PY - 2019/1

Y1 - 2019/1

N2 - The coatings with gradually varying chemical composition and structure were obtained by PECVD method from methane precursor and various admixtures of Ar. The composition of emitted gases and triboemission behaviour were studied for these coatings and correlated with the coating properties and deposition conditions. A new analytical approach was developed that allowed identification of the emitted gas species with much higher accuracy than conventional techniques. For the first time, triboemission of alkanes higher than propane was observed. By the application of kinetic model to the analysis of triboemission time series, chemical and structural degradation in carbon coatings could be traced in course of tribological tests.

AB - The coatings with gradually varying chemical composition and structure were obtained by PECVD method from methane precursor and various admixtures of Ar. The composition of emitted gases and triboemission behaviour were studied for these coatings and correlated with the coating properties and deposition conditions. A new analytical approach was developed that allowed identification of the emitted gas species with much higher accuracy than conventional techniques. For the first time, triboemission of alkanes higher than propane was observed. By the application of kinetic model to the analysis of triboemission time series, chemical and structural degradation in carbon coatings could be traced in course of tribological tests.

KW - Degradation

KW - Hydrogenated amorphous carbon

KW - Mass-spectrometry

KW - Tribochemistry

UR - http://www.scopus.com/inward/record.url?scp=85052130594&partnerID=8YFLogxK

U2 - 10.1016/j.triboint.2018.08.023

DO - 10.1016/j.triboint.2018.08.023

M3 - Article

AN - SCOPUS:85052130594

SN - 0301-679X

VL - 129

SP - 177

EP - 190

JO - Tribology International

JF - Tribology International

ER -

Evolution of tribologically induced chemical and structural degradation in hydrogenated a-C coatings

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this