TY - JOUR
T1 - Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts
AU - Khokarale, Santosh G.
AU - García-Suárez, Eduardo J.
AU - Fehrmann, Rasmus
AU - Riisager, Anders
N1 - Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/5/23
Y1 - 2017/5/23
N2 - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.
AB - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.
KW - carbonylation
KW - fixed-bed technology
KW - ionic liquids
KW - palladium
KW - supported ionic liquid phase catalysis
UR - https://www.scopus.com/pages/publications/85017466378
U2 - 10.1002/cctc.201601428
DO - 10.1002/cctc.201601428
M3 - Article
AN - SCOPUS:85017466378
SN - 1867-3880
VL - 9
SP - 1824
EP - 1829
JO - ChemCatChem
JF - ChemCatChem
IS - 10
ER -