One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route

Víctor Oestreicher; Matías Jobbágy

doi:10.1021/la402260m

One pot synthesis of Mg₂Al(OH)₆Cl·1.5H ₂O layered double hydroxides: The epoxide route

Víctor Oestreicher
, Matías Jobbágy^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Pure Mg₂Al(OH)₆Cl·1.5H₂O layered double hydroxide (LDH) has been synthesized at room temperature by a one-pot method, homogeneously driven by chloride-assisted glycidol rupture (epoxide route). Well-defined nanoplatelet texture was achieved and the LDH crystallization mechanism discussed. Nanoplatelets self-assemble in the form of highly oriented films with excellent optical properties. LDH films exhibited stability toward detaching in aqueous solutions and allowed a fast anionic exchange preserving a high transparency.

Original language	English
Pages (from-to)	12104-12109
Number of pages	6
Journal	Langmuir
Volume	29
Issue number	39
DOIs	https://doi.org/10.1021/la402260m
Publication status	Published - 1 Oct 2013
Externally published	Yes

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title = "One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route",

abstract = "Pure Mg2Al(OH)6Cl·1.5H2O layered double hydroxide (LDH) has been synthesized at room temperature by a one-pot method, homogeneously driven by chloride-assisted glycidol rupture (epoxide route). Well-defined nanoplatelet texture was achieved and the LDH crystallization mechanism discussed. Nanoplatelets self-assemble in the form of highly oriented films with excellent optical properties. LDH films exhibited stability toward detaching in aqueous solutions and allowed a fast anionic exchange preserving a high transparency.",

author = "V{\'i}ctor Oestreicher and Mat{\'i}as Jobb{\'a}gy",

year = "2013",

month = oct,

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doi = "10.1021/la402260m",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides

T2 - The epoxide route

AU - Oestreicher, Víctor

AU - Jobbágy, Matías

PY - 2013/10/1

Y1 - 2013/10/1

N2 - Pure Mg2Al(OH)6Cl·1.5H2O layered double hydroxide (LDH) has been synthesized at room temperature by a one-pot method, homogeneously driven by chloride-assisted glycidol rupture (epoxide route). Well-defined nanoplatelet texture was achieved and the LDH crystallization mechanism discussed. Nanoplatelets self-assemble in the form of highly oriented films with excellent optical properties. LDH films exhibited stability toward detaching in aqueous solutions and allowed a fast anionic exchange preserving a high transparency.

AB - Pure Mg2Al(OH)6Cl·1.5H2O layered double hydroxide (LDH) has been synthesized at room temperature by a one-pot method, homogeneously driven by chloride-assisted glycidol rupture (epoxide route). Well-defined nanoplatelet texture was achieved and the LDH crystallization mechanism discussed. Nanoplatelets self-assemble in the form of highly oriented films with excellent optical properties. LDH films exhibited stability toward detaching in aqueous solutions and allowed a fast anionic exchange preserving a high transparency.

UR - https://www.scopus.com/pages/publications/84885008720

U2 - 10.1021/la402260m

DO - 10.1021/la402260m

M3 - Article

AN - SCOPUS:84885008720

SN - 0743-7463

VL - 29

SP - 12104

EP - 12109

JO - Langmuir

JF - Langmuir

IS - 39

ER -

One pot synthesis of Mg₂Al(OH)₆Cl·1.5H ₂O layered double hydroxides: The epoxide route

Abstract

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