TY - JOUR
T1 - Polymer + cosolvent systems. Part 6. - Influence of preferential solvation on unperturbed dimensions of the poly(methyl methacrylate) chain
AU - Katime, Issa A.
AU - Ochoa, José R.
AU - Teijón, José M.
PY - 1985
Y1 - 1985
N2 - The thermodynamic behaviour of syndiotactic poly(methyl methacrylate) (PMMA) has been studied in CCl4(1) + methanol(2), CCl4(1) + propan-1-ol(2) and CCl4(1) + butan-1-ol(2) cosolvent mixtures. When the preferential sorption coefficient, λ, is negative, the best cosolvent mixture is CCl4(1) + butan-1-ol(2), but when λ is positive the CCl4(1) + methanol(2) cosolvent mixture is best. The results obtained are discussed as a function of the local solvent composition, x2.
AB - The thermodynamic behaviour of syndiotactic poly(methyl methacrylate) (PMMA) has been studied in CCl4(1) + methanol(2), CCl4(1) + propan-1-ol(2) and CCl4(1) + butan-1-ol(2) cosolvent mixtures. When the preferential sorption coefficient, λ, is negative, the best cosolvent mixture is CCl4(1) + butan-1-ol(2), but when λ is positive the CCl4(1) + methanol(2) cosolvent mixture is best. The results obtained are discussed as a function of the local solvent composition, x2.
UR - https://www.scopus.com/pages/publications/0005238103
U2 - 10.1039/F29858100783
DO - 10.1039/F29858100783
M3 - Article
AN - SCOPUS:0005238103
SN - 0300-9238
VL - 81
SP - 783
EP - 788
JO - Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
JF - Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
IS - 6
ER -