Abstract
In this paper the Poly(methyl methaerylate) (3)/CCl4 (1) 1-propanol (2) and poly (methyl methaerylate) (PMMA) (3)/CCl4 (1)/1-butanol (2) cosolvent mixtures are studied at 303 K by light scattering, viscometry and interferometry. An inversion in solvation has been found in both systems, in the alcohol content ranging between 25 and 30 vol% depending of the 1-alkanol which is used in the cosolvent mixture.
| Original language | English |
|---|---|
| Pages (from-to) | 559-562 |
| Number of pages | 4 |
| Journal | Polymer Journal |
| Volume | 15 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Aug 1983 |
| Externally published | Yes |
Keywords
- Excess gibbs free energy
- Liquid order
- Mixtures
- Preferential adsorption coefficient
- Self-association