Polymer-supported manganese porphyrin catalysts - Peptide-linker promoted chemoselectivity

Emilie Brulé; King Kuok Hii; Yolanda R. De Miguel

doi:10.1039/b502149a

Polymer-supported manganese porphyrin catalysts - Peptide-linker promoted chemoselectivity

Emilie Brulé, King Kuok Hii, Yolanda R. De Miguel^*

^*Corresponding author for this work

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Abstract

Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.

Original language	English
Pages (from-to)	1971-1976
Number of pages	6
Journal	Organic and Biomolecular Chemistry
Volume	3
Issue number	10
DOIs	https://doi.org/10.1039/b502149a
Publication status	Published - 21 May 2005

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title = "Polymer-supported manganese porphyrin catalysts - Peptide-linker promoted chemoselectivity",

abstract = "Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.",

author = "Emilie Brul{\'e} and Hii, {King Kuok} and {De Miguel}, {Yolanda R.}",

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AU - Brulé, Emilie

AU - Hii, King Kuok

AU - De Miguel, Yolanda R.

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Y1 - 2005/5/21

N2 - Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.

AB - Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.

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DO - 10.1039/b502149a

M3 - Article

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AN - SCOPUS:19944409380

SN - 1477-0520

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EP - 1976

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

Polymer-supported manganese porphyrin catalysts - Peptide-linker promoted chemoselectivity

Abstract

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