Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

Raquel Rodríguez; María J. Barandiaran; José M. Asua

doi:10.1016/j.polymer.2007.12.027

Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

Raquel Rodríguez
, María J. Barandiaran
, José M. Asua^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

Original language	English
Pages (from-to)	691-696
Number of pages	6
Journal	Polymer
Volume	49
Issue number	3
DOIs	https://doi.org/10.1016/j.polymer.2007.12.027
Publication status	Published - 4 Feb 2008
Externally published	Yes

Keywords

Limiting conversion
Miniemulsion polymerization
Silicone-acrylic

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10.1016/j.polymer.2007.12.027

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title = "Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization",

abstract = "The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.",

keywords = "Limiting conversion, Miniemulsion polymerization, Silicone-acrylic",

author = "Raquel Rodr{\'i}guez and Barandiaran, \{Mar{\'i}a J.\} and Asua, \{Jos{\'e} M.\}",

year = "2008",

month = feb,

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doi = "10.1016/j.polymer.2007.12.027",

language = "English",

volume = "49",

pages = "691--696",

journal = "Polymer",

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T1 - Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

AU - Rodríguez, Raquel

AU - Barandiaran, María J.

AU - Asua, José M.

PY - 2008/2/4

Y1 - 2008/2/4

N2 - The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

AB - The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

KW - Limiting conversion

KW - Miniemulsion polymerization

KW - Silicone-acrylic

UR - https://www.scopus.com/pages/publications/38549134406

U2 - 10.1016/j.polymer.2007.12.027

DO - 10.1016/j.polymer.2007.12.027

M3 - Article

AN - SCOPUS:38549134406

SN - 0032-3861

VL - 49

SP - 691

EP - 696

JO - Polymer

JF - Polymer

IS - 3

ER -

Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

Abstract

Keywords

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