Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

N. Almenara; S. Azpeitia; M. A. Garralda; M. A. Huertos

doi:10.1039/C8DT03703E

Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

N. Almenara
, S. Azpeitia
, M. A. Garralda^*
, M. A. Huertos

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Efficient catalytic reduction of CDCl₃ and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(iii) complex {Rh(H)[SiMe₂(o-C₆H₄SMe)](PPh₃)₂}[BAr^F ₄] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the hydrodehalogenation of CDCl₃.

Original language	English
Pages (from-to)	16225-16231
Number of pages	7
Journal	Dalton Transactions
Volume	47
Issue number	45
DOIs	https://doi.org/10.1039/C8DT03703E
Publication status	Published - 2018
Externally published	Yes

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title = "Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes",

abstract = "Efficient catalytic reduction of CDCl3 and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(iii) complex \{Rh(H)[SiMe2(o-C6H4SMe)](PPh3)2\}[BArF 4] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the hydrodehalogenation of CDCl3.",

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note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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AU - Almenara, N.

AU - Azpeitia, S.

AU - Garralda, M. A.

AU - Huertos, M. A.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - Efficient catalytic reduction of CDCl3 and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(iii) complex {Rh(H)[SiMe2(o-C6H4SMe)](PPh3)2}[BArF 4] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the hydrodehalogenation of CDCl3.

AB - Efficient catalytic reduction of CDCl3 and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(iii) complex {Rh(H)[SiMe2(o-C6H4SMe)](PPh3)2}[BArF 4] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the hydrodehalogenation of CDCl3.

UR - https://www.scopus.com/pages/publications/85056935555

U2 - 10.1039/C8DT03703E

DO - 10.1039/C8DT03703E

M3 - Article

C2 - 30393797

AN - SCOPUS:85056935555

SN - 1477-9226

VL - 47

SP - 16225

EP - 16231

JO - Dalton Transactions

JF - Dalton Transactions

IS - 45

ER -

Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes

Abstract

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