Sequestering CO 2 by Mineralization into Useful Nesquehonite-Based Products

  • Fredrik Paul Glasser*
  • , Guillaume Jauffret
  • , Jennie Morrison
  • , Jose Luis Galvez-Martos
  • , Naomi Patterson
  • , Mohammed Salah Eldin Imbabi
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

66 Citations (Scopus)

Abstract

The precipitation of magnesium hydroxy-carbonate hydrates has been suggested as a route to sequester CO2 into solids. We report the development of self-cementing compositions based on nesquehonite, MgCO 3 · 3 H 2 O, that are made from CO 2 -containing gas streams, the CO 2 being separated from other gases by its high solubility in alkaline water, while magnesium is typically provided by waste desalination brines. Precipitation conditions are adjusted to optimize the formation of nesquehonite and the crystalline solid can readily be washed free of chloride. Products can be prepared to achieve self-cementation following two routes: (i) thermal activation of the nesquehonite then rehydration of the precursor or (ii) direct curing of a slurry of nesquehonite. The products thus obtained contain ~30 wt% CO 2 and could form the basis for a new generation of lightweight, thermally insulating boards, blocks, and panels, with sufficient strength for general construction.

Original languageEnglish
Article number3
JournalFrontiers in Energy Research
Volume4
Issue numberFEB
DOIs
Publication statusPublished - 2016
Externally publishedYes

Keywords

  • CO sequestration
  • Construction products
  • Desalination brines
  • Magnesium carbonates
  • Mineralization

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