Shape memory polyurethanes based on polyols derived from renewable resources

M. A. Corcuera; A. Saralegi; B. Fernandez-d'Arlas; I. Mondragon; A. Eceiza

doi:10.1002/masy.201251135

Shape memory polyurethanes based on polyols derived from renewable resources

M. A. Corcuera^*
, A. Saralegi
, B. Fernandez-d'Arlas
, I. Mondragon
, A. Eceiza

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Segmented polyurethanes have been synthesized employing polyols derived from renewable resources, semicrystalline or amorphous in nature, as soft segment, and an aliphatic (1,6-hexamethylene diisocyanate, HDI) or aromatic (4,40- diphenylmethane diisocyanate, MDI) diisocyanate and 1,4-butanediol (BD) as hard segment using two-step bulk polymerization procedure. The effect of soft and hard segment structure and hard segment content on thermal, mechanical and shape memory properties has been studied by means of differential scanning calorimetry, tensile tests and tensile tests performed using a thermal chamber.

Original language	English
Pages (from-to)	197-201
Number of pages	5
Journal	Macromolecular Symposia
Volume	321-322
Issue number	1
DOIs	https://doi.org/10.1002/masy.201251135
Publication status	Published - Dec 2012
Externally published	Yes

Keywords

Polyols
Polyurethanes
Renewable resources
Shape memory

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10.1002/masy.201251135

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title = "Shape memory polyurethanes based on polyols derived from renewable resources",

abstract = "Segmented polyurethanes have been synthesized employing polyols derived from renewable resources, semicrystalline or amorphous in nature, as soft segment, and an aliphatic (1,6-hexamethylene diisocyanate, HDI) or aromatic (4,40- diphenylmethane diisocyanate, MDI) diisocyanate and 1,4-butanediol (BD) as hard segment using two-step bulk polymerization procedure. The effect of soft and hard segment structure and hard segment content on thermal, mechanical and shape memory properties has been studied by means of differential scanning calorimetry, tensile tests and tensile tests performed using a thermal chamber.",

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year = "2012",

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doi = "10.1002/masy.201251135",

language = "English",

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pages = "197--201",

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T1 - Shape memory polyurethanes based on polyols derived from renewable resources

AU - Corcuera, M. A.

AU - Saralegi, A.

AU - Fernandez-d'Arlas, B.

AU - Mondragon, I.

AU - Eceiza, A.

PY - 2012/12

Y1 - 2012/12

N2 - Segmented polyurethanes have been synthesized employing polyols derived from renewable resources, semicrystalline or amorphous in nature, as soft segment, and an aliphatic (1,6-hexamethylene diisocyanate, HDI) or aromatic (4,40- diphenylmethane diisocyanate, MDI) diisocyanate and 1,4-butanediol (BD) as hard segment using two-step bulk polymerization procedure. The effect of soft and hard segment structure and hard segment content on thermal, mechanical and shape memory properties has been studied by means of differential scanning calorimetry, tensile tests and tensile tests performed using a thermal chamber.

AB - Segmented polyurethanes have been synthesized employing polyols derived from renewable resources, semicrystalline or amorphous in nature, as soft segment, and an aliphatic (1,6-hexamethylene diisocyanate, HDI) or aromatic (4,40- diphenylmethane diisocyanate, MDI) diisocyanate and 1,4-butanediol (BD) as hard segment using two-step bulk polymerization procedure. The effect of soft and hard segment structure and hard segment content on thermal, mechanical and shape memory properties has been studied by means of differential scanning calorimetry, tensile tests and tensile tests performed using a thermal chamber.

KW - Polyols

KW - Polyurethanes

KW - Renewable resources

KW - Shape memory

UR - https://www.scopus.com/pages/publications/84874228628

U2 - 10.1002/masy.201251135

DO - 10.1002/masy.201251135

M3 - Article

AN - SCOPUS:84874228628

SN - 1022-1360

VL - 321-322

SP - 197

EP - 201

JO - Macromolecular Symposia

JF - Macromolecular Symposia

IS - 1

ER -

Shape memory polyurethanes based on polyols derived from renewable resources

Abstract

Keywords

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