Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

Phillip Malcho; Eduardo J. Garcia-Suarez; Uffe Vie Mentzel; Christian Engelbrekt; Anders Riisager

doi:10.1039/c4dt01629g

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

Phillip Malcho
, Eduardo J. Garcia-Suarez
, Uffe Vie Mentzel
, Christian Engelbrekt
, Anders Riisager^*

^*Corresponding author for this work

Technical University of Denmark

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

Original language	English
Pages (from-to)	17230-17235
Number of pages	6
Journal	Dalton Transactions
Volume	43
Issue number	46
DOIs	https://doi.org/10.1039/c4dt01629g
Publication status	Published - 14 Dec 2014
Externally published	Yes

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abstract = "Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.",

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AU - Malcho, Phillip

AU - Garcia-Suarez, Eduardo J.

AU - Mentzel, Uffe Vie

AU - Engelbrekt, Christian

AU - Riisager, Anders

N1 - Publisher Copyright: © the Partner Organisations 2014.

PY - 2014/12/14

Y1 - 2014/12/14

N2 - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

AB - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

UR - https://www.scopus.com/pages/publications/84908632233

U2 - 10.1039/c4dt01629g

DO - 10.1039/c4dt01629g

M3 - Article

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AN - SCOPUS:84908632233

SN - 1477-9226

VL - 43

SP - 17230

EP - 17235

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

Abstract

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