Thermodynamic properties of the PMMA-acetonitrile-1,4-dioxane system

Issa Katime; José Ramon Ochoa

doi:10.1039/F19878302289

Thermodynamic properties of the PMMA-acetonitrile-1,4-dioxane system

Issa Katime^*
, José Ramon Ochoa

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Thermodynamic properties of atactic poly(methylmethacrylate) in an acetonitrile-1,4-dioxane binary mixture have been studied at 298 K by viscometry and laser light scattering. Both techniques make evident a strong synergistic effect with its maximum close to U₂ = 70% 1,4-dioxane. The preferential sorption parameter λ as obtained by laser light scattering is practically equal to zero over the whole composition range. The experimental values compare favourably with those obtained theoretically from several ternary solution theories.

Original language	English
Pages (from-to)	2289-2300
Number of pages	12
Journal	Physical Chemistry Chemical Physics
Volume	83
Issue number	8
DOIs	https://doi.org/10.1039/F19878302289
Publication status	Published - 1987
Externally published	Yes

Access to Document

10.1039/F19878302289

Cite this

@article{71da3d03ca5a49bb8a2bd62f89e7f281,

title = "Thermodynamic properties of the PMMA-acetonitrile-1,4-dioxane system",

abstract = "Thermodynamic properties of atactic poly(methylmethacrylate) in an acetonitrile-1,4-dioxane binary mixture have been studied at 298 K by viscometry and laser light scattering. Both techniques make evident a strong synergistic effect with its maximum close to U2 = 70\% 1,4-dioxane. The preferential sorption parameter λ as obtained by laser light scattering is practically equal to zero over the whole composition range. The experimental values compare favourably with those obtained theoretically from several ternary solution theories.",

author = "Issa Katime and Ochoa, \{Jos{\'e} Ramon\}",

year = "1987",

doi = "10.1039/F19878302289",

language = "English",

volume = "83",

pages = "2289--2300",

journal = "Physical Chemistry Chemical Physics",

issn = "0300-9599",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Thermodynamic properties of the PMMA-acetonitrile-1,4-dioxane system

AU - Katime, Issa

AU - Ochoa, José Ramon

PY - 1987

Y1 - 1987

N2 - Thermodynamic properties of atactic poly(methylmethacrylate) in an acetonitrile-1,4-dioxane binary mixture have been studied at 298 K by viscometry and laser light scattering. Both techniques make evident a strong synergistic effect with its maximum close to U2 = 70% 1,4-dioxane. The preferential sorption parameter λ as obtained by laser light scattering is practically equal to zero over the whole composition range. The experimental values compare favourably with those obtained theoretically from several ternary solution theories.

AB - Thermodynamic properties of atactic poly(methylmethacrylate) in an acetonitrile-1,4-dioxane binary mixture have been studied at 298 K by viscometry and laser light scattering. Both techniques make evident a strong synergistic effect with its maximum close to U2 = 70% 1,4-dioxane. The preferential sorption parameter λ as obtained by laser light scattering is practically equal to zero over the whole composition range. The experimental values compare favourably with those obtained theoretically from several ternary solution theories.

UR - https://www.scopus.com/pages/publications/0348214367

U2 - 10.1039/F19878302289

DO - 10.1039/F19878302289

M3 - Article

AN - SCOPUS:0348214367

SN - 0300-9599

VL - 83

SP - 2289

EP - 2300

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 8

ER -

Thermodynamic properties of the PMMA-acetonitrile-1,4-dioxane system

Abstract

Access to Document

Other files and links

Fingerprint

Cite this