TY - JOUR
T1 - Carbons supported bio-ionic liquids
T2 - Stability and catalytic activity
AU - García-Suárez, Eduardo J.
AU - Moriel, Patricia
AU - Menéndez-Vázquez, Carmen
AU - Montes-Morán, Miguel A.
AU - García, Ana B.
PY - 2011/10
Y1 - 2011/10
N2 - [Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.
AB - [Chol][Pro] was supported on different porous carbon materials. Subsequently, the catalytic activity of the heterogeneous systems in the Michael reaction between cyclohexanone and β-nitrostyrene was studied. Excellent conversions and high diasteroselectivities were attained by supporting [Chol][Pro] on the heat treated mesoporous carbons. The stability of the [Chol][Pro] and consequently, its catalytic activity were strongly influenced by the textural and surface chemical properties of the carbon supports.
KW - Carbon materials
KW - Heterogeneous organocatalysis
KW - Michael addition
KW - Supported Bio-IL
KW - [Chol][Pro]
UR - https://www.scopus.com/pages/publications/79960198769
U2 - 10.1016/j.micromeso.2011.04.023
DO - 10.1016/j.micromeso.2011.04.023
M3 - Article
AN - SCOPUS:79960198769
SN - 1387-1811
VL - 144
SP - 205
EP - 208
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
IS - 1-3
ER -