Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

Ana M. Gómez; Aitor Barrio; Iñigo Amurrio; Serafín Valverde; Slawomir Jarosz; J. Cristóbal López

doi:10.1016/j.tetlet.2006.06.133

Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

Ana M. Gómez^*
, Aitor Barrio
, Iñigo Amurrio
, Serafín Valverde
, Slawomir Jarosz
, J. Cristóbal López

^*Autor correspondiente de este trabajo

CSIC - Instituto de Química Orgánica General IQOG
Institute of Organic Chemistry of the Polish Academy of Sciences

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

21 Citas (Scopus)

Resumen

(Z)-exo-Glycals can be conveniently prepared in a convergent manner by Stille cross-coupling of (Z)-halo(Br,I)-exo-glycals and aryl or alkenyl stannanes, the latter are readily obtained by addition of tributylstannyl radicals to terminal alkynes.

Idioma original	Inglés
Páginas (desde-hasta)	6243-6246
Número de páginas	4
Publicación	Tetrahedron Letters
Volumen	47
N.º	35
DOI	https://doi.org/10.1016/j.tetlet.2006.06.133
Estado	Publicada - 28 ago 2006
Publicado de forma externa	Sí

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10.1016/j.tetlet.2006.06.133

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title = "Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes",

abstract = "(Z)-exo-Glycals can be conveniently prepared in a convergent manner by Stille cross-coupling of (Z)-halo(Br,I)-exo-glycals and aryl or alkenyl stannanes, the latter are readily obtained by addition of tributylstannyl radicals to terminal alkynes.",

author = "G{\'o}mez, \{Ana M.\} and Aitor Barrio and I{\~n}igo Amurrio and Seraf{\'i}n Valverde and Slawomir Jarosz and L{\'o}pez, \{J. Crist{\'o}bal\}",

year = "2006",

month = aug,

day = "28",

doi = "10.1016/j.tetlet.2006.06.133",

language = "English",

volume = "47",

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journal = "Tetrahedron Letters",

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T1 - Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

AU - Gómez, Ana M.

AU - Barrio, Aitor

AU - Amurrio, Iñigo

AU - Valverde, Serafín

AU - Jarosz, Slawomir

AU - López, J. Cristóbal

PY - 2006/8/28

Y1 - 2006/8/28

N2 - (Z)-exo-Glycals can be conveniently prepared in a convergent manner by Stille cross-coupling of (Z)-halo(Br,I)-exo-glycals and aryl or alkenyl stannanes, the latter are readily obtained by addition of tributylstannyl radicals to terminal alkynes.

AB - (Z)-exo-Glycals can be conveniently prepared in a convergent manner by Stille cross-coupling of (Z)-halo(Br,I)-exo-glycals and aryl or alkenyl stannanes, the latter are readily obtained by addition of tributylstannyl radicals to terminal alkynes.

UR - https://www.scopus.com/pages/publications/33746298940

U2 - 10.1016/j.tetlet.2006.06.133

DO - 10.1016/j.tetlet.2006.06.133

M3 - Article

AN - SCOPUS:33746298940

SN - 0040-4039

VL - 47

SP - 6243

EP - 6246

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

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