Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria. Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25°c

Yolanda Belaustegi; Maria A. Olazabal; Juan M. Madariaga

doi:10.1016/S0378-3812(98)00459-2

Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria. Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25°c

Yolanda Belaustegi
, Maria A. Olazabal
, Juan M. Madariaga^*

^*Autor correspondiente de este trabajo

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

32 Citas (Scopus)

Resumen

The Modified Bromley's Methodology (MBM) has been used to construct the basic chemical model between Fe(III) and OH^- and the halide ligands Cl^-, Br^- and F^- in NaClO₄ medium at 25°C, obtaining the thermodynamic constants and the corresponding interaction parameters for each equilibrium. This basic model has been extended to KNO₃, HCl, and KCl media obtaining the corresponding interaction parameters. The applicability of the model is also discussed.

Idioma original	Inglés
Páginas (desde-hasta)	21-31
Número de páginas	11
Publicación	Fluid Phase Equilibria
Volumen	155
N.º	1
DOI	https://doi.org/10.1016/S0378-3812(98)00459-2
Estado	Publicada - 5 feb 1999
Publicado de forma externa	Sí

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10.1016/S0378-3812(98)00459-2

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abstract = "The Modified Bromley's Methodology (MBM) has been used to construct the basic chemical model between Fe(III) and OH- and the halide ligands Cl-, Br- and F- in NaClO4 medium at 25°C, obtaining the thermodynamic constants and the corresponding interaction parameters for each equilibrium. This basic model has been extended to KNO3, HCl, and KCl media obtaining the corresponding interaction parameters. The applicability of the model is also discussed.",

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Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria. Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25°c. / Belaustegi, Yolanda; Olazabal, Maria A.; Madariaga, Juan M.
En: Fluid Phase Equilibria, Vol. 155, N.º 1, 05.02.1999, p. 21-31.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

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AU - Olazabal, Maria A.

AU - Madariaga, Juan M.

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KW - Activity coefficients

KW - Chemical model

KW - Equilibrium

KW - Interactions

KW - Thermodynamics

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