Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

María I. Mangione; Rolando A. Spanevello; Daniela Minudri; Daniel Heredia; Luciana Fernandez; Luis Otero; Fernando Fungo

doi:10.1016/j.electacta.2016.04.154

Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

María I. Mangione
, Rolando A. Spanevello^*
, Daniela Minudri
, Daniel Heredia
, Luciana Fernandez
, Luis Otero
, Fernando Fungo

^*Autor correspondiente de este trabajo

Consejo Nacional de Investigaciones Científicas y Técnicas
Universidad Nacional de Rio Cuarto

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

37 Citas (Scopus)

Resumen

A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

Idioma original	Inglés
Páginas (desde-hasta)	143-151
Número de páginas	9
Publicación	Electrochimica Acta
Volumen	207
DOI	https://doi.org/10.1016/j.electacta.2016.04.154
Estado	Publicada - 20 jul 2016
Publicado de forma externa	Sí

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title = "Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films",

abstract = "A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.",

keywords = "Dendrimeric Polymers, Electrodeposition, Optoelectronic",

author = "Mangione, \{Mar{\'i}a I.\} and Spanevello, \{Rolando A.\} and Daniela Minudri and Daniel Heredia and Luciana Fernandez and Luis Otero and Fernando Fungo",

year = "2016",

month = jul,

day = "20",

doi = "10.1016/j.electacta.2016.04.154",

language = "English",

volume = "207",

pages = "143--151",

journal = "Electrochimica Acta",

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T1 - Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

AU - Mangione, María I.

AU - Spanevello, Rolando A.

AU - Minudri, Daniela

AU - Heredia, Daniel

AU - Fernandez, Luciana

AU - Otero, Luis

AU - Fungo, Fernando

PY - 2016/7/20

Y1 - 2016/7/20

N2 - A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

AB - A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.

KW - Dendrimeric Polymers

KW - Electrodeposition

KW - Optoelectronic

UR - https://www.scopus.com/pages/publications/84966297187

U2 - 10.1016/j.electacta.2016.04.154

DO - 10.1016/j.electacta.2016.04.154

M3 - Article

AN - SCOPUS:84966297187

SN - 0013-4686

VL - 207

SP - 143

EP - 151

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films

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