Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C

Y. Belaustegi; N. Etxebarria; M. A. Olazabal; L. A. Fernández; J. M. Madariaga

doi:10.1007/BF00972926

Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C

Y. Belaustegi^*
, N. Etxebarria
, M. A. Olazabal
, L. A. Fernández
, J. M. Madariaga

^*Autor correspondiente de este trabajo

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10 Citas (Scopus)

Resumen

The aggregation and mixed species formation equilibria of tri-n-dodecylammonium chloride (TLAHCl) and tri-n-dodecylammonium nitrate (TLAHNO₃) dissolved in toluene have been studied by vapor pressure osmometry at 40°C. The experimental data can be best fit by the formation of the aggregates (TLAHCl)₂ (log β_2.0 = 1.35±0.06), (TLAHNO₃)₂ (log β_0.2 = 1.75±0.20), (TLAHNO₃)₃ (log β_0.3 = 3.6±0.1), and the mixed species (TLAHCl)(TLAHNO₃)₂ (log β_1.2 = 3.3±0.2).

Idioma original	Inglés
Páginas (desde-hasta)	1113-1124
Número de páginas	12
Publicación	Journal of Solution Chemistry
Volumen	25
N.º	11
DOI	https://doi.org/10.1007/BF00972926
Estado	Publicada - nov 1996
Publicado de forma externa	Sí

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@article{30e1af61ae464e3cbdcab2cf54a3da3b,

title = "Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C",

abstract = "The aggregation and mixed species formation equilibria of tri-n-dodecylammonium chloride (TLAHCl) and tri-n-dodecylammonium nitrate (TLAHNO3) dissolved in toluene have been studied by vapor pressure osmometry at 40°C. The experimental data can be best fit by the formation of the aggregates (TLAHCl)2 (log β2.0 = 1.35±0.06), (TLAHNO3)2 (log β0.2 = 1.75±0.20), (TLAHNO3)3 (log β0.3 = 3.6±0.1), and the mixed species (TLAHCl)(TLAHNO3)2 (log β1.2 = 3.3±0.2).",

keywords = "Aggregation equilibria, Mixed species formation equilibria, Toluene, Tri-n-dodecylammonium chloride and nitrate, Vapor pressure osmometry",

author = "Y. Belaustegi and N. Etxebarria and Olazabal, \{M. A.\} and Fern{\'a}ndez, \{L. A.\} and Madariaga, \{J. M.\}",

year = "1996",

month = nov,

doi = "10.1007/BF00972926",

language = "English",

volume = "25",

pages = "1113--1124",

journal = "Journal of Solution Chemistry",

issn = "0095-9782",

publisher = "Springer New York",

number = "11",

}

Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C. / Belaustegi, Y.; Etxebarria, N.; Olazabal, M. A. et al.
En: Journal of Solution Chemistry, Vol. 25, N.º 11, 11.1996, p. 1113-1124.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C

AU - Belaustegi, Y.

AU - Etxebarria, N.

AU - Olazabal, M. A.

AU - Fernández, L. A.

AU - Madariaga, J. M.

PY - 1996/11

Y1 - 1996/11

N2 - The aggregation and mixed species formation equilibria of tri-n-dodecylammonium chloride (TLAHCl) and tri-n-dodecylammonium nitrate (TLAHNO3) dissolved in toluene have been studied by vapor pressure osmometry at 40°C. The experimental data can be best fit by the formation of the aggregates (TLAHCl)2 (log β2.0 = 1.35±0.06), (TLAHNO3)2 (log β0.2 = 1.75±0.20), (TLAHNO3)3 (log β0.3 = 3.6±0.1), and the mixed species (TLAHCl)(TLAHNO3)2 (log β1.2 = 3.3±0.2).

AB - The aggregation and mixed species formation equilibria of tri-n-dodecylammonium chloride (TLAHCl) and tri-n-dodecylammonium nitrate (TLAHNO3) dissolved in toluene have been studied by vapor pressure osmometry at 40°C. The experimental data can be best fit by the formation of the aggregates (TLAHCl)2 (log β2.0 = 1.35±0.06), (TLAHNO3)2 (log β0.2 = 1.75±0.20), (TLAHNO3)3 (log β0.3 = 3.6±0.1), and the mixed species (TLAHCl)(TLAHNO3)2 (log β1.2 = 3.3±0.2).

KW - Aggregation equilibria

KW - Mixed species formation equilibria

KW - Toluene

KW - Tri-n-dodecylammonium chloride and nitrate

KW - Vapor pressure osmometry

UR - https://www.scopus.com/pages/publications/0008166008

U2 - 10.1007/BF00972926

DO - 10.1007/BF00972926

M3 - Article

AN - SCOPUS:0008166008

SN - 0095-9782

VL - 25

SP - 1113

EP - 1124

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

IS - 11

ER -

Interactions of metal extractant reagents. IX. Aggregation and mixed species equilibria of tri-n-dodecylammonium chloride and nitrate in toluene at 40°C

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