Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

Raquel Rodríguez; María J. Barandiaran; José M. Asua

doi:10.1016/j.polymer.2007.12.027

Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

Raquel Rodríguez
, María J. Barandiaran
, José M. Asua^*

^*Autor correspondiente de este trabajo

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

22 Citas (Scopus)

Resumen

The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

Idioma original	Inglés
Páginas (desde-hasta)	691-696
Número de páginas	6
Publicación	Polymer
Volumen	49
N.º	3
DOI	https://doi.org/10.1016/j.polymer.2007.12.027
Estado	Publicada - 4 feb 2008
Publicado de forma externa	Sí

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@article{c99755bd8c644a9d8b554dc6c7a61956,

title = "Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization",

abstract = "The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.",

keywords = "Limiting conversion, Miniemulsion polymerization, Silicone-acrylic",

author = "Raquel Rodr{\'i}guez and Barandiaran, \{Mar{\'i}a J.\} and Asua, \{Jos{\'e} M.\}",

year = "2008",

month = feb,

day = "4",

doi = "10.1016/j.polymer.2007.12.027",

language = "English",

volume = "49",

pages = "691--696",

journal = "Polymer",

issn = "0032-3861",

number = "3",

}

TY - JOUR

T1 - Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

AU - Rodríguez, Raquel

AU - Barandiaran, María J.

AU - Asua, José M.

PY - 2008/2/4

Y1 - 2008/2/4

N2 - The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

AB - The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.

KW - Limiting conversion

KW - Miniemulsion polymerization

KW - Silicone-acrylic

UR - https://www.scopus.com/pages/publications/38549134406

U2 - 10.1016/j.polymer.2007.12.027

DO - 10.1016/j.polymer.2007.12.027

M3 - Article

AN - SCOPUS:38549134406

SN - 0032-3861

VL - 49

SP - 691

EP - 696

JO - Polymer

JF - Polymer

IS - 3

ER -

Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization

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