(Pro2H+)2(TCNQ.-)2 · TCNQ: An amino acid derived semiconductor

Xiaohu Qu; Jinzhen Lu; Chuan Zhao; John F. Boas; Boujemaa Moubaraki; Keith S. Murray; Amal Siriwardana; Alan M. Bond; Lisandra L. Martin

doi:10.1002/anie.201005406

(Pro₂H⁺)₂(TCNQ^.-)₂ · TCNQ: An amino acid derived semiconductor

Xiaohu Qu^*
, Jinzhen Lu
, Chuan Zhao
, John F. Boas
, Boujemaa Moubaraki
, Keith S. Murray
, Amal Siriwardana
, Alan M. Bond
, Lisandra L. Martin

^*Autor correspondiente de este trabajo

Monash University

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

33 Citas (Scopus)

Resumen

An attractive couple: (Pro₂H⁺)₂(TCNQ ^.-)₂ · TCNQ (TCNQ=tetracyanoquinodimethane) contains an H-bonding network that supports a layered structure, composed of alternating TCNQ anions and proline cations (see picture). The cation is formed by two zwitterionic proline amino acids supported by a proton bridge between the carboxylates, whereas the anionic component involves a neutral TCNQ molecule sandwiched between two TCNQ^.-.

Idioma original	Inglés
Páginas (desde-hasta)	1589-1592
Número de páginas	4
Publicación	Angewandte Chemie - International Edition
Volumen	50
N.º	7
DOI	https://doi.org/10.1002/anie.201005406
Estado	Publicada - 11 feb 2011
Publicado de forma externa	Sí

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10.1002/anie.201005406

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abstract = "An attractive couple: (Pro2H+)2(TCNQ .-)2 · TCNQ (TCNQ=tetracyanoquinodimethane) contains an H-bonding network that supports a layered structure, composed of alternating TCNQ anions and proline cations (see picture). The cation is formed by two zwitterionic proline amino acids supported by a proton bridge between the carboxylates, whereas the anionic component involves a neutral TCNQ molecule sandwiched between two TCNQ.-.",

keywords = "amino acids, biomaterials, proline, semiconductors, tetracyanoquinodimethane",

author = "Xiaohu Qu and Jinzhen Lu and Chuan Zhao and Boas, \{John F.\} and Boujemaa Moubaraki and Murray, \{Keith S.\} and Amal Siriwardana and Bond, \{Alan M.\} and Martin, \{Lisandra L.\}",

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AU - Boas, John F.

AU - Moubaraki, Boujemaa

AU - Murray, Keith S.

AU - Siriwardana, Amal

AU - Bond, Alan M.

AU - Martin, Lisandra L.

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AB - An attractive couple: (Pro2H+)2(TCNQ .-)2 · TCNQ (TCNQ=tetracyanoquinodimethane) contains an H-bonding network that supports a layered structure, composed of alternating TCNQ anions and proline cations (see picture). The cation is formed by two zwitterionic proline amino acids supported by a proton bridge between the carboxylates, whereas the anionic component involves a neutral TCNQ molecule sandwiched between two TCNQ.-.

KW - amino acids

KW - biomaterials

KW - proline

KW - semiconductors

KW - tetracyanoquinodimethane

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