Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

Phillip Malcho; Eduardo J. Garcia-Suarez; Uffe Vie Mentzel; Christian Engelbrekt; Anders Riisager

doi:10.1039/c4dt01629g

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

Phillip Malcho
, Eduardo J. Garcia-Suarez
, Uffe Vie Mentzel
, Christian Engelbrekt
, Anders Riisager^*

^*Autor correspondiente de este trabajo

Technical University of Denmark

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

11 Citas (Scopus)

Resumen

Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

Idioma original	Inglés
Páginas (desde-hasta)	17230-17235
Número de páginas	6
Publicación	Dalton Transactions
Volumen	43
N.º	46
DOI	https://doi.org/10.1039/c4dt01629g
Estado	Publicada - 14 dic 2014
Publicado de forma externa	Sí

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abstract = "Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.",

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AU - Malcho, Phillip

AU - Garcia-Suarez, Eduardo J.

AU - Mentzel, Uffe Vie

AU - Engelbrekt, Christian

AU - Riisager, Anders

PY - 2014/12/14

Y1 - 2014/12/14

N2 - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

AB - Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.

UR - https://www.scopus.com/pages/publications/84908632233

U2 - 10.1039/c4dt01629g

DO - 10.1039/c4dt01629g

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JO - Dalton Transactions

JF - Dalton Transactions

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Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

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